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1.
为探明气候变化下干旱半干旱地区湿草甸参考作物蒸散发(ET0)影响因子,使用FAO 56 P-M模型对科尔沁湿草甸ET0进行模拟,利用涡度相关系统对模型的适用性进行评价,并通过通径分析及指标敏感性分析对ET0的影响因子进行辨识。结果表明:(1)小时尺度模拟精度最高,日尺度次之,月尺度较差,小时尺度上晴、阴、雨3种天气条件下模拟效果不同,晴天最优,阴雨天较差。(2)ET0年内变化呈单峰曲线状,生长季明显高于非生长季,集中在3—10月,占全年89.79%。生长季典型晴天ET0逐小时分布特征遵循倒“U”单峰型变化规律。(3)通径分析结果显示,对ET0的通径系数以及对回归方程估测可靠程度E的总贡献均表现为VPD(饱和水汽压差) > Tmin(最低气温) > Rn(冠层表面净辐射)>u2(2 m高度风速),即VPD为影响ET0最重要的因子;指标敏感性分析中,在去除VPD后引起的E变化最大,说明ET0VPD的变化最为敏感,其次为u2TminRn。  相似文献   
2.
戴德求  包海梅  刘爽  尹锋 《岩石学报》2020,36(6):1850-1856
富Al球粒是原始球粒陨石中一种矿物岩石学特征介于富钙铝包体(CAIs)和镁铁质硅酸盐球粒之间的特殊集合体,所以常常认为富Al球粒在认识CAIs和镁铁质硅酸盐球粒形成演化过程中的相互联系具有特殊意义。然而,对富Al球粒的初始物质组成以及形成演化过程一直存在较多争议,而氧同位素组成研究能够对球粒演化和早期星云环境等提供重要的信息。在本文中我们报导了来自Kainsaz(1937年降落于俄罗斯,CO3型)碳质球粒陨石中的2个富Al球粒(编号K1-CH1和K2-CH2)的矿物岩石学和氧同位素组成特征。K1-CH1的矿物组成主要为橄榄石、低钙辉石和富钙长石,K2-CH2为橄榄石和富钙长石。2个球粒中的矿物均具有贫~(16)O同位素组成特征。K1-CH1中矿物的△~(17)O组成基本上位于2个区间:-11.1‰~-8.7‰和-3.9‰~0.4‰;而K2-CH2的△~(17)O介于-6.6‰~-0.6‰之间,且具有从中部至边部升高的趋势。矿物岩石学和氧同位素特征表明,这2个富Al球粒的初始物质组成为富CAIs和镁铁质硅酸盐。在球粒熔融结晶过程中,与贫~(16)O同位素组成(△~(17)O:-8.7‰~-7.8‰)的星云发生了氧同位素交换。球粒形成后,发生迁移进入陨石母体,在相对更贫~(16)O同位素组成(△~(17)O:-0.6‰~0.4‰)的母体中(流体参与)发生变质作用,并再次发生了氧同位素交换。  相似文献   
3.
To study the crustal movement in the vicinity of the epicenter before the Zhangye MS5.0 earthquake in 2019, the characteristics of crustal deformation before the earthquake are discussed through the GPS velocity field analysis based on the CMONOC data observed from GPS. The baseline time series between two continuous GPS stations and the strain time series of an area among several stations are analyzed in the epicenter area. The resulting time series of baseline azimuth around the epicenter reflects that the energy of the fault in the northern margin of Qilian Mountain is accumulated continuously before 2017. Besides, the movement trend of azimuth slows down after 2017, indicating the stress accumulation on both sides of the seismogenic fault zone has reached a certain degree. The first shear strain and EW-direction linear strain in the epicentral area of the Zhangye MS5.0 earthquake remain steady after 2017, and the surface strain rate decreases gradually after 2016. It is illustrated that there is an obvious deformation loss at the epicentral region three years before the earthquake, indicating that a certain degree of strain energy is accumulated in this area before the earthquake.  相似文献   
4.
The high‐precision δ60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ60/58Ni NIST SRM 986 values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.  相似文献   
5.
This work presents new 87Sr/86Sr and δ88/86SrSRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ88/86SrSRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ88/86SrSRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ88/86SrSRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ88/86SrSRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ88/86SrSRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.  相似文献   
6.
Measurement of Ba isotope ratios of widely available reference materials is required for interlaboratory comparison of data. Here, we present new Ba isotope data for thirty‐four geological reference materials, including silicates, carbonates, river/marine sediments and soils. These reference materials (RMs) cover a wide range of compositions, with Ba mass fractions ranging from 6.4 to 1900 µg g?1, SiO2 from 0.62% to 90.36% m/m and MgO from 0.08% to 41.03% m/m. Accuracy and precision of our data were assessed by the analyses of duplicate samples and USGS rock RMs. Barium isotopic compositions for all RMs were in agreement with each other within uncertainty. The variation of δ138/134Ba in these RMs was up to 0.7‰. The shale reference sample, affected by a high degree of chemical weathering, had the highest δ138/134Ba (0.37 ± 0.03‰), while the stream sediment obtained from a tributary draining carbonate rocks was characterised by the lowest δ138/134Ba (?0.30 ± 0.05‰). Geochemical RMs play a fundamental role in the high‐precision and accurate determination of Ba isotopic compositions for natural samples with similar matrices. Analyses of these RMs could provide universal comparability for Ba isotope data and enable assessment of accuracy for interlaboratory data.  相似文献   
7.
Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ11B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ11B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO2 and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   
8.
It is widely accepted that ductility design improves the seismic capacity of structures worldwide. Nevertheless, inelastic deformation allows serious damage to occur in structures. Previous studies have shown that a certain level of postyield stiffness may reduce both the peak displacement and residual deformation of a structure. In recent years, several high-strength elastic materials, such as fiber-reinforced polymer (FRP) and high-strength steel bars, have been developed. Application of these materials can easily provide a structure with a much higher and more stable postyield stiffness. Many materials, members, and structures that incorporate both high-strength elastic materials and conventional materials show significant postyield hardening (PYH) behaviors. The significant postyield stiffness of PYH structures can help effectively reduce both peak and residual deformations, providing a choice when designing resilient structures. However, the findings of previous studies of structures with elastic-perfectly plastic (EPP) behavior or small postyield stiffness may not be accurate for PYH structures. The postyield stiffness of a structure must be considered an important primary structural parameter, in addition to initial stiffness, yielding strength, and ductility. In this paper, extensive time history and statistical analyses are carried out for PYH single–degree-of-freedom (SDOF) systems. The mean values and coefficients of variation of the peak displacement and residual deformation are obtained and discussed. A new R-μp-T-α relationship and damage index for PYH structures are proposed. A theoretical model for the calculation of residual deformation is also established. These models provide a basis for developing the appropriate seismic design and performance evaluation procedures for PYH structures.  相似文献   
9.
主要分析了构造抬升对水系和地形的影响和恢复,以从古生代灰岩围岩中大面积但零星出露的岩溶砾岩点为研究对象,对区域古水系和地形地貌恢复和反演做出了新的尝试。在收集资料和实测的基础上,尝试性探讨了利用稳定水体参照物高程反演抬升高度以及邻区山峰点的古高程、古水系,恢复区域上古地形地貌的技术方法。并以白彦地区为例,通过白彦岩溶砾岩的分布、产状、金刚石矿物含量、岩性等地质特征,恢复白彦地区古地形线、古水系位置和流向等古地理地貌,指出在白彦期时代,该区总体发育4个水系,邹城市大石墙水系、枣庄水系、平邑水系、费县水系,水系中金刚石含量较为丰富的砾岩点大多分布在凤凰山隆起中心,其中在平邑水系推测存在一个山地峡谷中的古湖泊。认为蒙山凸起中已知的常马庄地区的金伯利岩脉所含有金刚石可能主要供应平邑区水系,其他3个地区水系的金刚石可能来源于凤凰山及其东部隆起剥蚀地区。  相似文献   
10.
李科  张琳  刘福亮  贾艳琨 《岩矿测试》2020,39(5):753-761
实验室和研究人员所使用的碳、氮同位素标准物质一般由国际原子能机构(IAEA)获得,然而近年来,随着碳氮同位素在实验室质量监控、方法评价、仪器校准等方面的广泛应用,市场需求量不断增加, IAEA研制的碳、氮同位素标准物质的种类与数量逐渐不能满足科学研究快速发展的需求。我国急需研制适应当今分析技术水平的有机质碳氮同位素国家标准物质用以进行质量监控、方法评价、仪器校准。为保证量值传递精度,本文研制了4个有机化学物质的碳氮稳定同位素标准物质,其中3个为尿素样品,1个为L-谷氨酸。经检验4种标准物质的均匀性通过F值检验,标准物质的δ~(13)C和δ~(15)N值经过一年的稳定性检验,特征量值变化在测量方法允许的不确定度范围内,由此判定δ~(13)C和δ~(15)N值稳定性良好。由包括研制单位实验室在内的12家实验室协同定值,采用高温燃烧-气体同位素质谱法测定了δ~(13)C和δ~(15)N值,系列标准物质δ~(13)C和δ~(15)N认定值区间呈梯度分布,δ~(13)C值为-40‰~0‰,δ~(15)N值为-10‰~30‰,涵盖了我国天然样品中有机质碳氮稳定同位素组成范围;研制的系列标准物质δ~(13)C的定值扩展不确定度不大于0.08‰,δ~(15)N的定值扩展不确定度不大于0.09‰,定值水平与国际标准物质相当。该系列标准物质已被国家质检总局批准为国家一级标准物质,批准号为GBW04494~GBW04497。可被用于地质、生态、环境等多种样品δ~(13)C和δ~(15)N比值测定时的分析监控、仪器校准、方法评价、质量保证和质量监控。  相似文献   
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